Electron paramagnetic resonance study of free radicals inγ-irradiated single crystal of tris(glycine) calcium(II) dibromide
P Subramanian N Hariharan J Sobhanadri
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Tris(glycine) calcium(II) dibromide single crystal has been irradiated with aγ-source to produce free radicals and the irradiated sample has been subjected toepr studies. The observed spectra reveal that an NH4 radical is formed by rupturing glycine molecule due to irradiation. The unpaired electron is localized on the C-N bond. The proton hyperfine interaction on the unpaired spin shows orthorhombic symmetry and the spectroscopic splitting factor remains isotropic.
P Subramanian1 N Hariharan1 2 J Sobhanadri1 3
Volume 96, 2022
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