• Reinvestigation of the second negative (A2ΠuX2Πg) band system of O2+

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      https://www.ias.ac.in/article/fulltext/pram/007/05/0324-0333

    • Keywords

       

      O2+; rotational analysis; spin-orbit coupling constant

    • Abstract

       

      TheA2Πustate of O2+ was earlier established as an inverted state contrary to previous assumptions. The rotational analysis of a few more bands of theA-X system of O2+ has now been completed. These studies show that the spin-orbit coupling constantA in theA2Πustate gradually varies with the vibrational quantum numberν and is found to be positive forν⩾6. It has also been observed that the spia-rotation interaction is not negligible in theA2Πustate. The spin splitting constantγ is reported for various vibrational levels of this electronic state.

    • Author Affiliations

       

      G L Bhale1 N A Narasimham1

      1. Spectroscopy Division, Bhabha Atomic Research Centre, Bombay - 400085
    • Dates

       
  • Pramana – Journal of Physics | News

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