• Homogeneous catalyst containing Pd in the reduction of aryl azides to primary amines

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      https://www.ias.ac.in/article/fulltext/jcsc/134/0041

    • Keywords

       

      Aryl azides; Hydrogenation; Primary amines; BINAP.PdCl2.

    • Abstract

       

      Commercially available dichloro[2,2-bis(diphenylphosphino)-1,1-binaphthyl]palladium(II)(BINAP.PdCl2) homogeneous catalyst was used for the reduction of aryl azides to primary amines. Thereactions were carried out in water and yields above 95% were obtained in a short time. Sodium borohydridewas used as the reducing reagent. A number of aryl azide derivatives have been converted into primaryamines, thanks to the hydrogen gas released by sodium borohydride with the help of water and catalyst.

    • Graphical Abstract

       

      Synopsis Commercially available dichloro[2,2-bis(diphenylphosphino)-1,1-binaphthyl]palladium(II) (BINAP.PdCl2) homogeneous catalyst was used for the reduction of aryl azides to primary amines. The reactions were carried out in water and yields above 95% were obtained in a short time. Sodium borohydride was used as the reducing reagent. A number of aryl azide derivatives have been converted into primary amines, thanks to the hydrogen gas released by sodium borohydride with the help of water and catalyst.

    • Author Affiliations

       

      CANTOPCU E1 AYDINLI E1 GOKSU H1

      1. Kaynasli Vocational College, Duzce University, 81900 Duzce, Turkey
    • Dates

       
  • Journal of Chemical Sciences | News

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