• Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/134/0013

    • Keywords

       

      Iron; Chalcogen; Styrene chalcogenosulfonate; X-ray structure; Characterization.

    • Abstract

       

      In this contribution, we report the preparation of iron thiosulfonato complex CpFe(CO)2SeSO2CH=CHPh (1) and its selenosulfonato analogue CpFe(CO)2SeSO2CH=CHPh (2) featuring styrene moiety. 1and 2 are obtained by electrophilic attack of (μ-Ex)[CpFe(CO)2]2 (E = S; x = 2–4, E = Se; x = 1) on the sulfuratom of styrene sulfonyl chloride ClSO2CH=CHPh. The new compounds, 1 and 2 have been characterized byelemental analyses, IR, 1H-, 13C{1H}-NMR, UV–Vis spectroscopy and the structure of 2 is determined byX-ray crystallography.

    • Graphical Abstract

       

      In this contribution, we report the preparation of iron thiosulfonato complex CpFe(CO)2SeSO2CH=CHPh (1) and its selenosulfonato analogue CpFe(CO)2SeSO2CH=CHPh (2) featuring styrene moiety. 1 and 2 are obtained by electrophilic attack of (μ-Ex)[CpFe(CO)2]2 (E = S; x = 2–4, E = Se; x = 1) on the sulfur atom of styrene sulfonyl chloride ClSO2CH=CHPh. The new compounds, 1 and 2 have been characterized by elemental analyses, IR, 1H-, 13C{1H}-NMR, UV–Vis spectroscopy and the structure of 2 is determined by X-ray crystallography..

    • Author Affiliations

       

      MOHAMMAD EL-KHATEEB1 ALAA AL-MOMANI1 PILAR GARCIA-ORDUNA2 FERNANDO J LAHOZ2

      1. Chemistry Department, Jordan University of Science and Technology, Irbid 22110, Jordan
      2. Inorganic Chemistry Department, Institute for Chemical Synthesis and Homogeneous Catalysis, CSIC – University of Zaragoza, 50009 Zaragoza, Spain
    • Dates

       
  • Journal of Chemical Sciences | News

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2021-2022 Indian Academy of Sciences, Bengaluru.