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      https://www.ias.ac.in/article/fulltext/jcsc/133/0013

    • Keywords

       

      s-triazines; tri-s-triazines; 3+2 cyclo additions; high energy materials; nitrogen-rich compounds

    • Abstract

       

      This article describes the syntheses, characterization, and energetic properties of 4, 6-diazido-N,N-dimethyl-1, 3, 5-triazin-2-amine and 2, 4, 6-tris (5-(3, 5-dinitrophenyl)-1H-tetrazol-1-yl)-1, 3, 5-triazine. Also, this paper emphasizes the insensitive and thermally stable energetic molecules like melem, melemammonium perchlorate mixture, and hydrazinium cyamelurate. All these compounds possess good energetic properties viz., the heat of formation and heat of combustion.

    • Graphical Abstract

       

      Synthesis and characterizations and energetic properties of 4, 6-diazido-N, N-dimethyl-1, 3, 5-triazin-2-amine (3); 2, 4, 6-tris (5-(3, 5-dinitrophenyl)-1H-tetrazol-1-yl)-1, 3, 5-triazine (4) and hydrazinium cyamelurate (10) are described. The thermal stabilities, energetic properties and sensitivity parameters are compared with standard high-energy materials. (i) Syntheses and characterization of 4, 6-diazido-N, N-dimethyl-1, 3, 5-triazin-2-amine (3); 2, 4, 6-tris (5-(3, 5-dinitrophenyl)-1H-tetrazol-1-yl)-1, 3, 5-triazine (4) and hydrazinium cyamelurate (10) are described. (ii) Experimental energetic properties and sensitivity parameters of these compounds were discussed.

    • Author Affiliations

       

      MUDDAMARRI HANUMANTHA RAO1 VIKAS D GHULE2 KRISHNAMURTHI MURALIDHARAN1 3

      1. Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Hyderabad,Telangana 500 046, India
      2. Department of Chemistry, National Institute of Technology Kurukshetra, Kurukshetra, Haryana 136119,India
      3. School of Chemistry, University of Hyderabad, Hyderabad, Telangana 500 046, India
    • Dates

       
  • Journal of Chemical Sciences | News

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