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      https://www.ias.ac.in/article/fulltext/jcsc/132/0148

    • Keywords

       

      Kharasch–Sosnovsky reaction; Allylic C–H bond oxidation; tert-Butyl iodobenzoperoxoate; Alkenyl iodobenzoate; copper (I) iodide; Alkenes

    • Abstract

       

      The synthesis of new alkenyl iodobenzoate derivatives as allylic esters was investigated via the reaction of tert-butyl iodobenzoperoxoate with alkenes in the presence of copper salts. The best result was obtained using tert-butyl-iodobenzoperoxoate in the presence of copper (I) iodide (5 mol%) in refluxingacetonitrile with good yield (92%) in 32 h. The structure of peresters and alkenyl iodobenzoate derivatives were characterized on the basis of their FT-IR, 1HNMR, 13CNMR, and Mass spectra

    • Author Affiliations

       

      SAADI SAMADI1 AKRAM ASHOURI SHIVA MAJIDIAN HERSH I RASHID

      1. Laboratory of Asymmetric Synthesis, Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj 66177-15175, Iran
    • Dates

       
  • Journal of Chemical Sciences | News

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