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    • Synthesis of meso-substituted corroles and porphyrins using iodine as a catalyst

      ANSHU DANDIA SHIVE M S CHAUHAN

      Volume 132 Published: 10 September 2020 Article ID 0123

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/132/0123

    • Keywords

       

      Pyrrole; aldehydes; iodine; corrole; corrin; porphyrin

    • Abstract

       

      Different types of corroles and porphyrins are synthesized from substituted aldehydes and pyrrole. The current synthetic method involves iodine as catalyst and proceeds at room temperature itself. By varying the amounts of reactants (i.e., pyrrole and aldehydes), the corrole and porphyrins were obtained ingood to excellent yields. These products were characterized by 1H-NMR, UV-visible, and HRMS techniques. The reaction approach utilizes the readily available pyrrole and substituted aldehydes as starting materials and makes this reaction highly attractive in diversity-oriented synthesis

    • Author Affiliations

       

      ANSHU DANDIA SHIVE M S CHAUHAN1

      1. Bio-Organic Research Laboratory, Department of Chemistry, University of Delhi, Delhi 110 007, India

    • Dates

       
      Published
      10 September 2020
      Manuscript received
      15 March 2020
      Manuscript revised
      11 June 2020
      Accepted
      12 June 2020

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