Efforts toward the synthesis of (+)-Lyconadin A
SATISH KARELLA SADAGOPAN RAGHAVAN
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Synthetic efforts toward the synthesis of (?)-lyconadin A are described. B-Alkyl Suzuki coupling is utilized for combining 2-iodo cyclohexenone with the piperidine subunit. The piperidine subunit is derived from 5-bromo-3-nicotinic acid, and iodo cyclohexenone from commercially available (R)-pulegone. An intramolecular Michael reaction is employed for the creation of the C6-C7 bond.
SATISH KARELLA1 2 SADAGOPAN RAGHAVAN1 2
Volume 132, 2020
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