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      https://www.ias.ac.in/article/fulltext/jcsc/132/0087

    • Keywords

       

      Film catalyst; doctor blade; heterogeneous catalyst; Knoevenagel condensation; solvent-free

    • Abstract

       

      Novel film catalysts of the polystyrene (Ps) and trimethyl phosphate (P) nanoparticles were synthesized on glass substrates by soft chemistry using doctor blade method. Subsequently, the prepared Ps–P film catalysts were characterized by various techniques, including fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), density (d), polarizing microscope (PM), X-ray diffraction (XRD) and thermal analysis. According to the results, the structure and morphology of film catalysts were confirmed by all analyses. The Ps–P films, as heterogeneous solid catalysts, have demonstrated strong activity for Knoevenagel condensation, producing alkenes of high purity. The recovered yields are excellent, up to 96% in solvent-free conditions at room temperature. Further, the film catalysts have showed high stability, good reusability (up to five times) while maintaining their efficiency and productivity

    • Author Affiliations

       

      HALIMA EL AADAD1 ZAKARIA BENZEKRI2 SAID BOUKHRIS2 ABDELKRIM CHAHINE1

      1. Laboratory of Physico-Chemistry of Vitreous and Crystallized Materials (LPCVCM), Department of Chemistry, Faculty of Science, Ibn Tofail University, BP 133, 14000 Kenitra, Morocco
      2. Laboratory of Organic Chemistry, Organometallic and Theoretical, Department of Chemistry, Faculty of Sciences, Ibn Tofail University, BP 133, 14000 Kenitra, Morocco
    • Dates

       
  • Journal of Chemical Sciences | News

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