• Two efficient ligand-assisted systems of two different ionic Schiff base ligands for palladium chloride catalyzed in Suzuki-Miyaura reaction

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      https://www.ias.ac.in/article/fulltext/jcsc/132/0033

    • Keywords

       

      Schiff base ligands; ligand assisted system; Suzuki-Miyaura reaction.

    • Abstract

       

      The bis- methyl imidazolium chloride-salophen Schiff base ligand as cationic Schiff base ligand (L1) was synthesized by the reaction of methyl imidazoliumsalicylaldehyde chloride (S1) and phenylendiamine.The phenylendiamine was also reacted by monosodium 5-sulfonatosalycilaldehyde (S2) to give the bis-sodium sulfonate-salophen Schiff base ligand (L2) as the anionic ligand. These two ligands were characterized by the 1H-NMR, 13C-NMR, IR, UV–visible and mass spectroscopy, as well as elemental analysis.The ligand assisted PdCl2 catalyst was investigated in the Suzuki-Miyaura reaction by using the L1 and L2 as cationic and anionic Schiff base ligands and different reaction conditions such as temperature, solvent and mol% of PdCl2 were optimized. The results revealed that the anionic ligand assistance had a better activity forthe catalytic system of PdCl2 in Suzuki-Miyaura reaction

    • Author Affiliations

       

      FARZANEH NEHZAT GHOLAMHOSSEIN GRIVANI1

      1. School of Chemistry, Damghan University, Damghan 36715-364, Iran
    • Dates

       
  • Journal of Chemical Sciences | News

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