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      https://www.ias.ac.in/article/fulltext/jcsc/132/0022

    • Keywords

       

      Iron; Vinyl thiocarboxylate; Substitution; Structures

    • Abstract

       

      Half-sandwich iron thiocarboxylate complexes of the general formula CpFe(CO)2-SCOCH=C(R¢)(RR¢¢){R¢ = H, R¢¢ = Me, R¢ = R¢¢ = Me, R¢ = H, R¢¢ = CH=CHMe}) are obtained from the reaction of (l-Sx)[CpFe(CO)2]2 (x = 1–5) with the vinyl acid chlorides ClCOCH=C(R¢)(R¢¢). The substitution reaction of CpFe(CO)2SCOCH=C(R)Me with EPh3 produced the monosubstituted complexesCpFe(CO)(EPh3)SCOCH=C(R)Me (R = Me, E = P, R = H, E = As, Sb). All the new complexes have been characterized by UV-Vis, IR, 1H-NMR, 13C{1H}-NMR, 31P{1H}-NMR spectroscopy and elemental analysis.The solid state structures and the cyclic voltammetric measurements of CpFe(CO)2SCOCH=CMe2 andCpFe(CO)(PPh3)SCOCH=CMe2 were determined.

    • Author Affiliations

       

      MOHAMMAD EL-KHATEEB1 KHALEEL JASALI1 BATOOL AL-JUNEIDI1 HASSAN ABUL-FUTOUH2 HELMAR GORLS3 WOLFGANG WEIGAND3

      1. Chemistry Department, Jordan University of Science and Technology, Irbid 22110, Jordan
      2. Department of Pharmacy, Al-Zaytoonah University of Jordan, P.O. Box 130, Amman 11733, Jordan
      3. Institut fu¨r Anorganische und Analytische Chemie, Friedrich-Schiller-Universita¨t Jena, Humboldt Str. 8, 07743 Jena, Germany
    • Dates

       
  • Journal of Chemical Sciences | News

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