-
- Home
- Journals
- Journal of Chemical Sciences
- Volume 132
- All articles
-
Two acetylenedicarboxylato-bridged 4-styrylpyridine appended 1D coordination polymers: synthesis, structural characterization and variable temperature magnetism
BASUDEB DUTTA AKHTARUZZAMAN HIROKI SATO TAKASHIRO AKITSU ALEXANDRA M Z SLAWIN UDDALOK KAR CHITTARANJAN SINHA MOHAMMAD HEDAYETULLAH MIR
Volume 132 Published: January 2020 Article ID 0009
-
-
Fulltext
Click here to view fulltext PDF
Permanent link:
https://www.ias.ac.in/article/fulltext/jcsc/132/0009 -
Keywords
Coordination polymers ;crystal structure ;H-bonding ;transition metals ;variable temperature magnetic moment. -
Abstract
Two hitherto unknown one-dimensional coordination polymers (1D CPs) [M(adc)(4-spy)2 (H2O)2]n, (M = Mn(II) (1) and Co(II) (2); H2adc = acetylenedicarboxylic acid and 4-spy = 4-styrylpyridine) have been characterized by infrared spectra, elemental analysis, thermogravimetric analyses (TGA), powder X-ray diffraction (PXRD) patterns and single-crystal X-ray diffraction techniques. Both these compounds 1 and 2, are isostructural and construct 3D supramolecular networks by the combination of hydrogen bonding and C–H...p interactions. Interestingly, these two materials exhibit variable temperature magnetic moment
-
Author Affiliations
BASUDEB DUTTA1 AKHTARUZZAMAN1 HIROKI SATO2 TAKASHIRO AKITSU2 ALEXANDRA M Z SLAWIN3 UDDALOK KAR4 CHITTARANJAN SINHA4 MOHAMMAD HEDAYETULLAH MIR1
- Department of Chemistry, Aliah University, New Town, Kolkata 700 156, West Bengal, India
- Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162 8601, Japan
- School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, UK
- Department of Chemistry, Jadavpur University, Kolkata 700 032, West Bengal, India
-
Dates
- Published
- January 2020
- Manuscript received
- 26 June 2019
- Manuscript revised
- 20 August 2019
- Accepted
- 21 August 2019
-
-
Journal of Chemical Sciences
Volume 133, 2021
All articles
Continuous Article Publishing mode
-
Journal of Chemical Sciences | News
-
Editorial Note on Continuous Article Publication
Posted on July 25, 2019Click here for Editorial Note on CAP Mode
-