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      https://www.ias.ac.in/article/fulltext/jcsc/132/0009

    • Keywords

       

      Coordination polymers; crystal structure; H-bonding; transition metals; variable temperature magnetic moment.

    • Abstract

       

      Two hitherto unknown one-dimensional coordination polymers (1D CPs) [M(adc)(4-spy)2 (H2O)2]n, (M = Mn(II) (1) and Co(II) (2); H2adc = acetylenedicarboxylic acid and 4-spy = 4-styrylpyridine) have been characterized by infrared spectra, elemental analysis, thermogravimetric analyses (TGA), powder X-ray diffraction (PXRD) patterns and single-crystal X-ray diffraction techniques. Both these compounds 1 and 2, are isostructural and construct 3D supramolecular networks by the combination of hydrogen bonding and C–H...p interactions. Interestingly, these two materials exhibit variable temperature magnetic moment

    • Author Affiliations

       

      BASUDEB DUTTA1 AKHTARUZZAMAN1 HIROKI SATO2 TAKASHIRO AKITSU2 ALEXANDRA M Z SLAWIN3 UDDALOK KAR4 CHITTARANJAN SINHA4 MOHAMMAD HEDAYETULLAH MIR1

      1. Department of Chemistry, Aliah University, New Town, Kolkata 700 156, West Bengal, India
      2. Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162 8601, Japan
      3. School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, UK
      4. Department of Chemistry, Jadavpur University, Kolkata 700 032, West Bengal, India
    • Dates

       
  • Journal of Chemical Sciences | News

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