• Conceptual approach to the synthesis of symmetrical 1,3-diynes from b-bromo vinyl carboxylic acids

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      https://www.ias.ac.in/article/fulltext/jcsc/132/0004

    • Keywords

       

      b-bromo vinyl carboxylic acid; palladium; benzyne; terminal alkyne; 1,3-diyne

    • Abstract

       

      A conceptual route has been developed for the synthesis of 1,3-diyne from b-bromo vinyl carboxylic acids. The reaction of the b-bromo vinyl carboxylic acid with palladium catalyst is conceptually similar to the decomposition of 2-diazoniumbenzoic acid to benzyne. In the presence of palladium catalyst,the b-bromo vinyl carboxylic acid undergoes a fragmentation to generate terminal alkyne. The terminal alkyne undergoes dimerisation in the presence of palladium catalysts to produce the product 1,3-diyne.

    • Author Affiliations

       

      RAJU SINGHA1

      1. Department of Chemistry, Panskura Banamali College (Autonomous), Panskura R.S., Purba Medinipur 721 152, West Bengal, India
    • Dates

       
  • Journal of Chemical Sciences | News

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