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    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/131/10/0103

    • Keywords

       

      Dithiocarbonate; structure; synthesis; characterization.

    • Abstract

       

      The dithiocarbonato metal complexes M(k2S,S-S2CO)(k2P,P-dppf) {M= Ni, Pd, Pt; dppf=bis(diphenylphosphino)ferrocene} are obtained from the reaction of the metal(II) complexes [M(K2S,S-S2-COEt)2] with the dppf ligand or from the chloride substitution of M(k2P,P-dppf)Cl2 by the O-ethyldithiocabonatoanion. These complexes are produced by C-O bond cleavage by the O-ethyldithiocarbonato anion present in solution. These new complexes have been characterized by UV-Vis, NMR, IR spectroscopy and elemental analysis. The structures of the three complexes were further confirmed by single-crystal X-ray diffraction analysis.

    • Author Affiliations

       

      MOHAMMAD EL-KHATEEB1 QUSAY TANASH1 HASSAN ABUL-FUTOUH2 HELMAR GORLS3 WOLFGANG WEIGAND3

      1. Chemistry Department, Jordan University of Science and Technology, Irbid 22110, Jordan
      2. Department of Pharmacy, Al-Zaytoonah University of Jordan, P.O. Box 130, Amman 11733, Jordan
      3. Institut fur Anorganische und Analytische Chemie, Friedrich-Schiller-Universitat Jena, Humboldt Str. 8, 07743 Jena, Germany

    • Dates

       
      Published
      October 2019
      Manuscript received
      25 May 2019
      Manuscript revised
      15 July 2019
      Accepted
      16 July 2019

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