Dithiocarbonato nickel, palladium and platinum complexes bearing bis(diphenylphosphino)ferrocene: synthesis and X-ray structure determination
MOHAMMAD EL-KHATEEB QUSAY TANASH HASSAN ABUL-FUTOUH HELMAR GORLS WOLFGANG WEIGAND
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The dithiocarbonato metal complexes M(k2S,S-S2CO)(k2P,P-dppf) {M= Ni, Pd, Pt; dppf=bis(diphenylphosphino)ferrocene} are obtained from the reaction of the metal(II) complexes [M(K2S,S-S2-COEt)2] with the dppf ligand or from the chloride substitution of M(k2P,P-dppf)Cl2 by the O-ethyldithiocabonatoanion. These complexes are produced by C-O bond cleavage by the O-ethyldithiocarbonato anion present in solution. These new complexes have been characterized by UV-Vis, NMR, IR spectroscopy and elemental analysis. The structures of the three complexes were further confirmed by single-crystal X-ray diffraction analysis.
MOHAMMAD EL-KHATEEB1 QUSAY TANASH1 HASSAN ABUL-FUTOUH2 HELMAR GORLS3 WOLFGANG WEIGAND3
Volume 133, 2021
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