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      https://www.ias.ac.in/article/fulltext/jcsc/131/08/0084

    • Keywords

       

      Ni(II) dithiolene complex; synthesis; X-ray structure; electricity conduction

    • Abstract

       

      One nickel(II)-dithiolene complex bis(1,2-diphenylethylene-1,2-dithiolate)nickel(II) has been synthesized and crystallographically characterized. The complex is square planar at its metal centre. The compound in its solid-state is found to conduct electricity at room temperature. Variation of conduction is also found on raising the temperature. Instead of a metal…metal orbital overlap, the electron density is expected here to pass through some other covalent and electrostatic bonds of the compound in solid-state resulting in electricity conduction.

    • Author Affiliations

       

      ARGHYA DUTTA1 ARNAB CHATTERJEE1 KISHALAY BHAR2 ANINDITA BANERJEE3 RAJARSHI GHOSH1

      1. Department of Chemistry, The University of Burdwan, Burdwan 713 104, West Bengal, India
      2. Department of Chemistry, School of Chemical Science and Pharmacy, Bandar Sindri 305 817, Rajasthan, India
      3. Department of Physics, The University of Burdwan, Burdwan 713 104, West Bengal, India
    • Dates

       
    • Supplementary Material

       
  • Journal of Chemical Sciences | News

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