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Metal-free selective aryl C–H formylation co-controlled by 1,2,3-triazole and hydroxyl using DMSO as formyl source
XINYUAN MA WEIGEN DU WEI LIU YAOWEN LIU TIEBO XIAO YUBO JIANG
Volume 131 Issue 7 July 2019 Article ID 0055
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Permanent link:
https://www.ias.ac.in/article/fulltext/jcsc/131/07/0055 -
Keywords
1,4-disubstituted 1,2,3-triazoles ;metal-free ;C–H formylation ;site-selective ;DMSO -
Abstract
A facile and efficient method for direct C–H formylation of phenolated 1,4-disubstituted 1,2,3-triazoles using DMSO as the formyl source has been developed. The reaction proceeded smoothly under metal-free conditions with good functional group tolerance and high selectivity co-controlled by the triazole ring and hydroxyl group.
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Author Affiliations
XINYUAN MA1 WEIGEN DU1 WEI LIU2 YAOWEN LIU1 TIEBO XIAO1 YUBO JIANG1
- Faculty of Science, Kunming University of Science and Technology, Kunming 650500, China
- School of Pharmacy, Nantong University, Nantong 226001, China
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Dates
- Published
- July 2019
- Manuscript received
- 12 February 2019
- Manuscript revised
- 5 April 2019
- Accepted
- 16 April 2019
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Supplementary Material
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Journal of Chemical Sciences
Volume 135, 2023
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