1. Home
    2. Journals
    3. Journal of Chemical Sciences
    4. Volume 130
    5. Issue 12

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/130/12/0171

    • Keywords

       

      Cage compounds; MnO2 oxidation; Diels–Alder reaction; [2+2] photocycloaddition; acid-promoted rearrangement; D3-Trishomocubanes

    • Abstract

       

      The synthesis of substituted cage [4.4.2]propellanes and D3-trishomocubanes bearing spiro linkage have been assembled with the aid of Diels–Alder reaction and ring-rearrangement as key steps. Here, readily available 1,4-hydroquinone, isoprene, spiro[2.4]hepta-4,6-diene and spiro[4.4]nona-1,3-diene were usedas starting materials. The unusual rearrangement of cage propellanes with zinc/acetic acid produced D3-trishomocubanes in good yields.

    • Author Affiliations

       

      SAMBASIVARAO KOTHA1 SUBBA RAO CHEEKATLA

      1. Department of Chemistry, Indian Institute of Technology-Bombay, Powai, India

    • Dates

       
      Published
      December 2018
      Manuscript received
      27 August 2018
      Manuscript revised
      Accepted
      15 October 2018

    • Supplementary Material

       

  • Journal of Chemical Sciences | News

© 2023-2024 Indian Academy of Sciences, Bengaluru.

Contact | Site index