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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/130/09/0116

    • Keywords

       

      Chromium(III) complexes; catalytic activities; polymerization; oxalate ion

    • Abstract

       

      The cis- and trans-potassium bis(oxalato)diaquochromates(III) have been studied towards their catalytic activity for the 2-chloroallyl alcohol oligomerization. The geometric isomerism effect on the oligomerization products under mild reaction conditions has been investigated. The molecular masses andtactic structures of obtained poly(2-chloroallyl alcohols) have been compared and analyzed. The mechanisms of oligomerization processes have been proposed. It has been proven that two studied complexes – cis-K[Cr(C2O4)2(OH2)22] and trans-K[Cr(C2O4)2(OH2) 2]·3H2O are highly active catalysts for the oligomerization of the beta-olefin derivative.

    • Author Affiliations

       

      JOANNA DRZEZDZON1 LECH CHMURZYNSKI DAGMARA JACEWICZ

      1. Faculty of Chemistry, University of Gdansk, Wita Stwosza 63, 80-308 Gdansk, Poland
    • Dates

       
  • Journal of Chemical Sciences | News

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