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    • Keywords


      Electrochemical energy storage; Li-S battery; carbon–sulfur interaction; XPS.

    • Abstract


      Effective trapping of polysulfides within the carbon cathode host strongly depends on intrinsic C–S interactions. We report herein a systematic study of the influence of S-loading process on C–S interactions in MWCNT/S composites prepared by three commonly used industry-friendly methods, namely, mechanical solidstate mixing, infiltration method from a solution of S in CS2, and chemical deposition by disproportionation reaction of sodium sulfide and sodium thiosulfate. FESEM and TEM studies reveal strikingly different morphologies of the resulting MWCNT/S composites. XPS and Raman studies indicate different extents of recovery of π bonds in MWCNT due to varying degrees of C–S interfacial interactions in the composites. Furthermore, it is found that the C/O atomic ratio in the composites plays a crucial role: the higher the C/O valuethe better is the S-confinement. These subtle physical changes induced by C–S interactions in the composites can be related to electrochemical performance when tested in Li-S coin cells. It is found that the best results (high initial capacity of 1143 mAh g -1 and better capacity retention) could be achieved when the solution infiltration method was used for S-loading. This conclusion is further validated by using activated carbon as S-host.

    • Author Affiliations



      1. CSIR-Central Glass and Ceramic Research Institute, Kolkata, West Bengal 700 032, India
      2. Institute of Nano Science and Technology, Mohali 160 062, India
    • Dates

    • Supplementary Material

  • Journal of Chemical Sciences | News

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