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      https://www.ias.ac.in/article/fulltext/jcsc/130/07/0099

    • Keywords

       

      Allene; allenylphosphine oxide; enynone; ynamide; P(III) isothiocyanate; X-ray structure.

    • Abstract

       

      Abstract. This perspective article is related to transformations (both catalytic and non-catalytic) involving allenes, alkynes/enynones/ynamides and isothiocyanates. Part of the work from the author’s group has been reviewed along with some new reactions of (i) allenylphosphonate/allenylphosphine oxide and (ii) a P(III) isothiocyanate. Thus, the allenylphosphine oxide Ph2P(O)C(Ph)=C=CH2 undergoes base (DBU) catalyzed addition to the β-ketophosphonate (OCH2CMe2CH2O)P(O)CH2C(O)CH3 at 90°C to afford the addition product Ph2P(O)C(Ph)=C(Me)CH[C(O)Me][P(O)(OCH2CMe2CH2O)]. In an analogous reaction, with DBU as the base at 140°C, isomeric vinylphosphine oxides (Z)-Ph2P(O)C(Ph)=C(Me)CH2[C(O)Me] and (E)-Ph2P(O)C(Ph)=C(Me)CH2[C(O)Me] were isolated. The E-isomer has been characterized by single crystal X-ray structure determination. In another set of studies, the reaction of P(III) isothiocyanate (OCH2CMe2CH2O)P(NCS) with N-(2-bromomethyl)sulfonamide afforded an unusual product with the formula(OCH2CMe2CH2O)P(O)SCH2CH2NHS(O)2-(C6H4-4-Me) as shown by X-ray structure determination. This result is different from that obtained in the recently reported analogous reaction using phenyl isothiocyanate.

    • Author Affiliations

       

      K C KUMARA SWAMY1 G GANGADHARARAO MANDALA ANITHA A LEELA SIVAKUMARI ALLA SIVA REDDY ADULA KALYANI SRINIVASARAO ALLU

      1. School of Chemistry, University of Hyderabad, Hyderabad, Telangana 500 046, India
    • Dates

       
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