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      https://www.ias.ac.in/article/fulltext/jcsc/130/06/0061

    • Keywords

       

      Diels-Alder reaction; steric interaction; restricted rotation; atropisomerism; conformational diastereomers.

    • Abstract

       

      Restricted rotation about the C(1)-N single bond in N, N-disubstituted 1-aminoanthracenes has been investigated. The synthesis, isolation and characterization of diastereomers arising out of the hindered rotationabout the CSP2-NSP2 single bond has been demonstrated. With unsymmetrical substituents on the Nitrogen atom,preferred conformations about the C(1)-N bond were observed.

    • Author Affiliations

       

      RUHIMA KHAN ANJANA NINGOMBAM MOIRANGTHEM DHANESHWAR SINGH1

      1. Department of Chemistry, Manipur University, Canchipur, Imphal 795 003, Manipur, India
    • Dates

       
    • Supplementary Material

       
  • Journal of Chemical Sciences | News

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