• Influence of alkene substituent in dictating the reaction course to form carbocycles or oxacycles during ring closing metathesis of acyclic trienes

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      Substituent effects; cyclization; carbocycles; oxygen heterocycles

    • Abstract


      Ring closing metathesis of acyclic trienes that can provide oxacycles or carbocycles has been investigated. It was found that a substituent on one of the alkene units determines the reaction course to provide either oxacycles or carbocyles exclusively irrespective of the ring size of the resulting compounds.

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