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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/129/05/0553-0559

    • Keywords

       

      Copper(II); Silver(I); Coordination polymer; Imidazolium ion; Ullmann coupling.

    • Abstract

       

      The silver(I) and copper(II)-imidazolium carboxylate coordination assemblies were derived from the reaction between corresponding carboxylic acid ligands and metal salts. These new metal derivatives depict a novel structural motif with variable chemical and thermal properties. These metal complexes act as potentialcatalysts in Ullmann coupling reactions. The imidazolium linker present in these complexes plays a role as both ligand and counter ion to balance the metal charge.

    • Author Affiliations

       

      GANESAN PRABUSANKAR1 CHATLA NAGA BABU1 GEMBALI RAJU1 NATARAJAN SAMPATH2

      1. Department of Chemistry, Indian Institute of Technology Hyderabad, Kandi, Sangareddy, Telangana 502 285, India
      2. School of Chemical and Biotechnology, SASTRA University, Tirumalaisamudram, Thanjavur, Tamil Nadu 613 401, India
    • Dates

       
    • Supplementary Material

       
  • Journal of Chemical Sciences | News

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