1. Home
    2. Journals
    3. Journal of Chemical Sciences
    4. Volume 129
    5. Issue 3

    • Hydrodechlorination of (CH₃)₃SiCHCl₂ over Pd, Ni, Co and Fe supported on AlF₃

      RATEB HINA ISAM ARAFA OMAR ENNAB

      Regular Article Volume 129 Issue 3 March 2017 pp 353-358

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/129/03/0353-0358

    • Keywords

       

      Hydrodechlorination; chloroorganosilane; Aluminium Fluoride; dichloromethyl trimethylsilane.

    • Abstract

       

      Gas phase hydrodechlorination (HDC) process of Me ₃SiCHCl ₂ was studied in a flow reactor at 200◦C using a 2% metal loading (w/w) of four different monometallic catalysts (Pd/AlF ₃, Ni/AlF₃,Co/AlF ₃and Fe/AlF ₃). The catalysts were prepared by sol-gel method and structurally examined by BET method, FT-IR and XPS techniques. The XPS technique showed that NiII, FeIII and CoIII exist as oxides. The major products in the HDC process of Me ₃SiCHCl ₂ were identified by GC and GC-MS and found to include Me ₃SiCH ₂Cl, Me ₃SiCl, and Me4Si. The effect of these catalysts on the quantitative conversion, selectivity and conversionrates are reported.

    • Author Affiliations

       

      RATEB HINA ISAM ARAFA OMAR ENNAB

      1. Dates

         
        Published
        6 March 2017
        Manuscript received
        9 December 2016
        Manuscript revised
        18 December 2016
        Accepted
        7 January 2017

    • Journal of Chemical Sciences | News

    © 2023-2024 Indian Academy of Sciences, Bengaluru.

    Contact | Site index