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    5. Issue 3

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/129/03/0301-0312

    • Keywords

       

      D-Fructose; primary amine; monofunctional organocatalyst; asymmetric aldol.

    • Abstract

       

      A new class of organocatalysts involving a primary amine as the only functional group is developed for catalytic asymmetric aldol reaction of cyclohexanone/ cyclopentanone with various aryl aldehydes in thepresence of benzoic acid as an additive at −10◦C. In an unexpected observation, the primary amine catalyzed reactions gave excellent yield and good to excellent stereoselectivity, while secondary amines were found to have little or no reactivity under similar reaction conditions.

    • Author Affiliations

       

      KHIANGTE VANLALDINPUIA PORAG BORA GHANASHYAM BEZ

      1. Dates

         
        Published
        6 March 2017
        Manuscript received
        7 September 2016
        Manuscript revised
        Accepted
        13 January 2017

      2. Supplementary Material

         

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