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    • Choline-based biodegradable ionic liquid catalyst for Mannich-type reaction

      PENG HUAN HU YULIN XING RONG FANG DONG

      Regular Article Volume 128 Issue 12 December 2016 pp 1855-1860

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/128/12/1855-1860

    • Keywords

       

      Mannich-type reaction; choline; Lewis-Brønsted acid; catalysis; biodegradation.

    • Abstract

       

      A three-component Mannich-type reaction of aromatic aldehydes, ketones, and amines was catalyzed by a novel choline-based acidic ionic liquid. The proposed catalyst was a Lewis-BrØnsted dual acid catalyst as well as water-tolerant. The β-amino carbonyl compounds were obtained at room temperature in reasonable to good yields ranging from 63 to 98%. After the reaction, the catalyst could be recycled and reused for 5 times without obvious decrease of the yield. Further, the catalyst was environment-friendly with a significant biodegradation rate.

    • Author Affiliations

       

      PENG HUAN1 HU YULIN2 XING RONG1 2 FANG DONG1 2

      1. College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, People’s Republic of China
      2. School of Chemistry & Environmental Engineering, Yancheng Teachers University, Yancheng 224002, People’s Republic of China

    • Dates

       
      Published
      7 December 2016
      Manuscript received
      2 February 2016
      Manuscript revised
      20 October 2016
      Accepted
      21 October 2016

    • Supplementary Material

       

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