• Study towards diversity oriented synthesis of optically active substituted cyclopentane fused carbocyclic and oxacyclic medium-sized rings: Competition between Grubbs-II catalyzed ring closing olefin metathesis and ring closing carbonyl-olefin metathesis

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      https://www.ias.ac.in/article/fulltext/jcsc/128/12/1831-1840

    • Keywords

       

      Diversity-oriented synthesis; bicyclic frameworks; ring closing metathesis; Grubbs-II catalyst; carbonyl-olefin metathesis.

    • Abstract

       

      A study towards diversity-oriented synthesis of optically active cyclopentane fused bicyclic frameworks has been accomplished. The common intermediate was prepared from commercially available starting material (S)-carvone. The observations on competition between Grubbs-II catalyzed ring closing metathesis (RCM) and ring closing carbonyl-olefin metathesis (RCCOM) were the key features of the study.

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