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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/128/06/0899-0904

    • Keywords

       

      o-Phthalic acid; Coordination polymer; X-ray Crystal structure; Copper(II); EPR; TGA.

    • Abstract

       

      Coordination polymer of Cu(II) bridged by o-phthalic acid alone is not known. The reaction of$CuCl_{2}.2H_{2}O$ with (2-butoxycarbonyl)benzoic acid yielded three dimensional coordination polymer bridged byo-phthalic acid. X-ray crystal structure shows structure with monoclinic P21/c space group. o-Phthalic acidmolecules act as bridge between two Cu(II), one carboxylate binds to one Cu(II) as bidentate while the othercarboxylate binds to another Cu(II) as monodentate. The four planar co-ordination positions of Cu(II) aresatisfied by two chelated carboxylates while fifth and sixth co-ordination positions are satisfied by monodentatecarboxylates. EPR and TGA of the coordination polymer are also reported.

    • Author Affiliations

       

      BABITA SARMA SAURAV BHARALI DIGANTA KUMAR DAS

      1. Dates

         
        Published
        8 June 2016
        Manuscript received
        21 April 2015
        Manuscript revised
        31 March 2016
        Accepted
        1 April 2016

      2. Supplementary Material

         

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