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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/128/06/0893-0898

    • Keywords

       

      Crystal structure; 1,3-bis(4-pyridyl)propane; Cu(I); inorganic linker; organic linker.

    • Abstract

       

      Two novel metal-organic coordination polymers $ [Cu_{2}(bpp)Cl_{2}]$ (1) and $[Cu_{2}(bpp)_{2}SO_{4}]$·DMF·$3H_{2}O (2) were prepared from the reactions of 1,3-bis(4-pyridyl)propane (bpp) with $CuCl_{2}$ and $CuSO_{4}$,respectively, which were characterized by single-crystal X-ray diffraction analysis, elemental analysis, IRspectroscopy and powder X-ray diffraction analysis. 1 features inorganic one-dimensional $ [Cu_{2}Cl_{2}]$ ribbons,which are linked by the bpp ligands to form a three-dimensional metal-organic framework exhibiting a 3,3,4-connected 3-nodal topology. 2 presents $[Cu_{2}SO_{4}]$ inorganic dinuclear secondary building blocks which are furtherconnected by the bpp ligands to construct a two-dimensional framework featuring flask-stacking appearance.They are typical examples of metal-organic framework constructed by the synergistic use of organic andinorganic linkers.

    • Author Affiliations

       

      ZHAOBO HU1 BO LI2 WENQIANG JU1 YUNING LIANG1 ZILU CHEN1

      1. State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, P R China
      2. College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061, P R China

    • Dates

       
      Published
      8 June 2016
      Manuscript received
      21 January 2016
      Manuscript revised
      21 April 2016
      Accepted
      24 April 2016

    • Supplementary Material

       

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