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    • Hydrothermal synthesis and electrochemical properties of a coordination polymer based on dinuclear (Pyrazinyl tetrazolate) Copper(II) cations and βOctamolybdate Anions

      SHAOBIN LI LI ZHANG HUIYUAN MA HAIJUN PANG

      Regular Article Volume 128 Issue 5 May 2016 pp 825-830

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/128/05/0825-0830

    • Keywords

       

      Polyoxometalates; octamolybdate; dinuclear copper complexes; electrochemical properties.

    • Abstract

       

      A hybrid compound $(H_{2}bbi)[Cu_{2}(pzta)_{2}(H_{2}O)_{2}][β-$Mo_{8}O_{26}$] (1) (pztaH = 5-(2-pyrazinyl) tetrazolate,bbi = 1,1'-(1,4-butanediyl)bis(imidazole), has been hydrothermally synthesized and characterized byelemental analysis, IR spectroscopy and single-crystal X-ray diffraction. In 1, the β-$Mo_{8}$ clusters link dinuclearcopper (II) complexes as bidentate connectors to form inorganic-organic chains. These chains and the $[H_{2}bbi]^{2+}$ counter-cations are fused together forming layers via hydrogen bonding interactions. The electrochemicalproperties of 1 were studied. The results indicate that 1 has an electrocatalytic activity towards thereduction of iodate ascribed to the Mo-centers.

    • Author Affiliations

       

      SHAOBIN LI1 2 LI ZHANG1 HUIYUAN MA1 HAIJUN PANG1

      1. Key Laboratory of Green Chemical Engineering and Technology, College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin, University of Science and Technology, Harbin 150040 China
      2. College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, China

    • Dates

       
      Published
      5 May 2016
      Manuscript received
      29 October 2015
      Manuscript revised
      20 January 2016
      Accepted
      14 March 2016

    • Supplementary Material

       

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