• Hydrothermal synthesis and electrochemical properties of a coordination polymer based on dinuclear (Pyrazinyl tetrazolate) Copper(II) cations and βOctamolybdate Anions

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/128/05/0825-0830

    • Keywords

       

      Polyoxometalates; octamolybdate; dinuclear copper complexes; electrochemical properties.

    • Abstract

       

      A hybrid compound $(H_{2}bbi)[Cu_{2}(pzta)_{2}(H_{2}O)_{2}][β-$Mo_{8}O_{26}$] (1) (pztaH = 5-(2-pyrazinyl) tetrazolate,bbi = 1,1'-(1,4-butanediyl)bis(imidazole), has been hydrothermally synthesized and characterized byelemental analysis, IR spectroscopy and single-crystal X-ray diffraction. In 1, the β-$Mo_{8}$ clusters link dinuclearcopper (II) complexes as bidentate connectors to form inorganic-organic chains. These chains and the $[H_{2}bbi]^{2+}$ counter-cations are fused together forming layers via hydrogen bonding interactions. The electrochemicalproperties of 1 were studied. The results indicate that 1 has an electrocatalytic activity towards thereduction of iodate ascribed to the Mo-centers.

    • Author Affiliations

       

      SHAOBIN LI1 2 LI ZHANG1 HUIYUAN MA1 HAIJUN PANG1

      1. Key Laboratory of Green Chemical Engineering and Technology, College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin, University of Science and Technology, Harbin 150040 China
      2. College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, China
    • Dates

       
    • Supplementary Material

       
  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.