• Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/128/02/0185-0191

    • Keywords

       

      p-chlorobenzaldehyde thiosemicarbazone; tetrahedral monomer; copper(I) halides; X-ray crystallography; hydrogen bonding; triphenylphosphine.

    • Abstract

       

      Reactions of copper(I) halides with p-chlorobenzaldehyde thiosemicarbazone (H1L) and triphenylphosphine in 1 : 1 : 2 molar ratio yielded complexes of stoichiometry, [CuX(𝜂1-S- H1L)(Ph3P)2] (X = I, 1: Br, 2; Cl, 3). All the three complexes were characterized using analytical (CHNS) and spectroscopic (IR, 1H NMR) techniques. The structure of complex 3 was confirmed by X-ray crystallography. It has been found to crystallize in the triclinic system with space group P-1 and unit cell parameters: a = 10.207(5) Å, b = 13.027(5) Å, c = 16.269(5) Å, 𝛼 = 100.054(5)°, 𝛽 = 99.228(5)° and 𝛾 = 97.234(5)°. This complex has distorted tetrahedral geometry with two phosphorus atoms from two triphenylphosphine ligands, thione sulfur of thiosemicarbazone ligand and chloride ion occupying the four corners of the tetrahedron. The structure of complex 3 was in contrast to sulfur-bridged dinuclear complex of copper(I) chloride with benzaldehydethiosemicarbazone, [Cu2Cl2(𝜇2-S-Hbtsc)2(Ph3P)2]·2H2O. The intermolecular H-bonding, Cl· · ·HCph, 2.733 Å and 𝜋 interactions, {CHph · · · 𝜋, 2.796; 2.776 Å} in this complex led to the formation of 1D chain. Two such 1D chains were cross-linked via, Cl· · ·HCph, 2.896 Å H-bonding to form a 2D network.

    • Author Affiliations

       

      Ashiq Khan1 Poonam Sharma1 Rajnikant2 Vivek K Gupta2 Naresh Padha2 Rekha Sharma1

      1. Department of Chemistry, Lovely Professional University, Phagwara, Punjab, India
      2. Post Graduate Department of Physics & Electronics, University of Jammu, Jammu Tawi 180006, India
    • Dates

       
    • Supplementary Material

       
  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.