• C(sp2)–C(sp2) cross coupling reaction catalyzed by a palladacycle phosphine complex: A simple and sustainable protocol in aqueous media

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      https://www.ias.ac.in/article/fulltext/jcsc/127/11/1919-1926

    • Keywords

       

      Palladium complex; Heck cross-coupling reaction; low catalyst loading; aerobic conditions.

    • Abstract

       

      The Heck reactions of various aryl halides with olefins using {[Ph2PCH2PPh2CH=C(O)(C10H7)] PdCl2} as efficient catalyst has been investigated. The mononuclear palladacycle complex showed excellent activity in aqueous phase including the C(sp2)–C(sp2) cross coupling reactions. The advantages of the protocol are high yields, short reaction time, a cleaner reaction profile and notable simplicity.

    • Author Affiliations

       

      Seyyed Javad Sabounchei1 Marjan Hosseinzadeh1

      1. Faculty of Chemistry, University of Bu–Ali Sina, Hamedan, 65174 Iran
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