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      https://www.ias.ac.in/article/fulltext/jcsc/127/10/1819-1826

    • Keywords

       

      Pyridine 2–carboxamide; silver(I) complexes; single crystal X-ray crystallography; photolumi- nescence; antimicrobial activity.

    • Abstract

       

      Two Ag(I) complexes, [Ag(HL)2]ClO4 (1) and [Ag(HL)2]NO3·H2O (2), where HL is pyridine 2– carboxamide, have been synthesized and characterized by various spectroscopic techniques. The X-ray crystal structural analyses indicate that both the complexes consist of slightly distorted square planar silver(I) ions and ligand-supported weak Ag⋯Ag metallophilic interactions. Both the complexes show photoluminescence in solid state and acetonitrile solution at room temperature. Antimicrobial studies have been performed with these silver(I) complexes against various gram +ve, gram −ve bacterial and fungal species.

    • Author Affiliations

       

      Sutapa Joardar1 Shounak Roy2 Suvendu Samanta2 Amit Kumar Dutta3

      1. Department of Biotechnology, Neotia Institute of Technology, Management and Science, Jhinga, Diamond Harbour Road, Amira, South 24 Parganas 743 368, India
      2. Department of Chemistry, Indian Institute of Engineering Science and Technology, Shibpur, Howrah 711 103, India
      3. Department of Chemistry, Bangabasi Morning College, 19, Rajkumar Chakraborty Sarani, Kolkata 700 009, India

    • Dates

       
      Published
      October 2015
      Manuscript received
      10 April 2015
      Manuscript revised
      15 July 2015
      Accepted
      20 July 2015

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