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      https://www.ias.ac.in/article/fulltext/jcsc/127/09/1513-1521

    • Keywords

       

      Supramolecule; one-dimension cluster; electrostatic attraction.

    • Abstract

       

      Three metal halide cluster supramolecular polymers, {(TBP)[Ag3Br6]}n (1), {(TBI)[Ag3Br6]}n (2) and {(TBP)[Ag3I6]}n (3) (TBP=1, 3, 5-tris(N-pyridinium methyl)benzene, TBI=1, 3, 5-tris(methylimidazole methyl)benzene), have been synthesized and characterized by thermoanalysis and spectroscopic methods, as well as single-crystal X-ray diffraction. Complexes 1, 2 and 3 all feature a one-dimensional chain structure, which is further extended by electrostatic attraction. The TGA, UV-Vis diffuse reflectance spectra in the solid state and optical band gap properties of the three complexes were also investigated.

    • Author Affiliations

       

      Yao Li1 Wen Li Zhang1 Hai Juan Du1 Chao-Hai Wang1 Ya Bin Lu1 Yun-Yin Niu1

      1. College of Chemistry and Molecular Engineering, Zhengzhou University, Henan 450001, P R China
    • Dates

       
  • Journal of Chemical Sciences | News

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