Crystal structure and solid-state properties of discrete hexa cationic trinuclear zinc triazole cluster
Chatla Naga Babu Paladugu Suresh Arruri Sathyanarayana Prasenjit Das Ganesan Prabusankar
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A linear trinuclear cluster of the type [{Zn3 (HTrz)6 (H2O)6}6+ (NO$_{3}^{−}$)6 (H2O)] (ZnT) has been synthesized by one-pot reaction between 1,2,4-triazole and Zn(NO3).6H2O. Molecule consists of three Zn2+ ions linearly connected by 1,2,4-triazole with tri-fold symmetry. The coordination geometry around the zinc centre is octahedral with zinc-zinc separation of 3.810 Å. The coordination environment of central Zn2+ ion is satisfied by nitrogen atoms of six 1,2,4-triazoles, while the geometry of terminal Zn2+ ions is fulfilled by nitrogen atoms of three 1,2,4-triazoles and three water molecules. The thermal and absorption properties of ZnT have been reported for the first time.
Chatla Naga Babu1 Paladugu Suresh1 Arruri Sathyanarayana1 Prasenjit Das1 Ganesan Prabusankar1
Volume 135, 2023
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