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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/127/08/1369-1373

    • Keywords

       

      Zinc; trizole; clusters; cationic compounds.

    • Abstract

       

      A linear trinuclear cluster of the type [{Zn3 (HTrz)6 (H2O)6}6+ (NO$_{3}^{−}$)6 (H2O)] (ZnT) has been synthesized by one-pot reaction between 1,2,4-triazole and Zn(NO3).6H2O. Molecule consists of three Zn2+ ions linearly connected by 1,2,4-triazole with tri-fold symmetry. The coordination geometry around the zinc centre is octahedral with zinc-zinc separation of 3.810 Å. The coordination environment of central Zn2+ ion is satisfied by nitrogen atoms of six 1,2,4-triazoles, while the geometry of terminal Zn2+ ions is fulfilled by nitrogen atoms of three 1,2,4-triazoles and three water molecules. The thermal and absorption properties of ZnT have been reported for the first time.

    • Author Affiliations

       

      Chatla Naga Babu1 Paladugu Suresh1 Arruri Sathyanarayana1 Prasenjit Das1 Ganesan Prabusankar1

      1. Department of Chemistry, Indian Institute of Technology Hyderabad, ODF Estate, Yeddumailaram, Telangana, India 502 205

    • Dates

       
      Published
      August 2015
      Manuscript received
      16 March 2015
      Manuscript revised
      21 April 2015
      Accepted
      24 April 2015

    • Supplementary Material

       

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