• Effect of 𝛽−𝛽′ fusion on metal ion complexation of porphycene

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    • Keywords

       

      Porphycene; porphyrin isomer; 𝛽−𝛽′ fused porphycene; 𝜋-extended porphycene; porphycene complexation; square-type-coordination.

    • Abstract

       

      Complexation of 𝛽−𝛽′ fused 𝜋-extended porphycene, namely dinaphthoporphycene was carried out successfully with copper(II) and its solid state structure shows a square-type planar N4-coordination core. The photophysical and electrochemical properties of this complex, along with the nickel(II) complex were also investigated. Further, electronic paramagnetic resonance (EPR) analysis of this complex is also reported.

    • Author Affiliations

       

      Tridib Sarma1 Pradeepta K Panda1

      1. School of Chemistry, University of Hyderabad, Hyderabad 500 046, India
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