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Synthesis and crystal structure of a wheel-shaped supramolecular coordination complex
Deepak Gupta Palanisamy Rajakannu Bhaskaran Shankar Firasat Hussain Malaichamy Sathiyendiran
Special issue on Chemical Crystallography Volume 126 Issue 5 September 2014 pp 1501-1506
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Keywords
Rhenium ;molecular ring ;anthraquinone ;non-covalent interactions ;supramolecules ;X-ray structure. -
Abstract
Supramolecular coordination complex (SCC) possessing spatially arranged three anthraquinone dimers in a slipped-cofacial orientation was achieved by the treatment of Re2(CO)10, 2-hydroxymethylanthraquinone and tritopic N-donor via fac-Re(CO)3-directed one pot approach. The off-set 𝜋-stacking and C≡O…H bonding interactions stabilize the ring structure.
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Author Affiliations
Deepak Gupta1 Palanisamy Rajakannu1 Bhaskaran Shankar1 Firasat Hussain1 Malaichamy Sathiyendiran1
- Department of Chemistry, University of Delhi, Delhi 110 007, India
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Dates
- Published
- September 2014
- Manuscript received
- 21 March 2014
- Accepted
- 8 April 2014
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Supplementary Material
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Journal of Chemical Sciences
Volume 135, 2023
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