Role of vanadium in Keggin heteropoly molybdate supported on titania catalysts for oxidation reactions
A Srivani K T Venkateswara Rao P S Sai Prasad N Lingaiah
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Vanadium-incorporated molybdophosporic acid catalysts supported on titania were prepared and characterized by FT-IR, X-ray diffraction and laser Raman spectroscopy. Characterization data reveals the incorporation of vanadium into the primary structure of Keggin ion of MPA. Catalysts activities were evaluated for oxidation of 1,2-benzenedimethanol using H2O2 and O2 as oxidants. Vanadium-containing catalysts showed high activity compared to their parent heteropoly acids. Oxidation ability depended on the number of V atoms present in Keggin heteropoly molybdate. Effect of reaction parameters on the oxidation ability was also evaluated.
A Srivani1 K T Venkateswara Rao1 P S Sai Prasad1 N Lingaiah1
Volume 135, 2023
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