Binding of reactive organophosphate by oximes via hydrogen bond
Andrea Pappalardo Maria E Amato Francesco P Ballistreri Valentina La Paglia Fragola Gaetano A Tomaselli Rosa Maria Toscano Giuseppe Trusso Sfrazzetto
Click here to view fulltext PDF
Permanent link:
https://www.ias.ac.in/article/fulltext/jcsc/125/04/0869-0873
In this contribution, the ability of simple oximes to bind a well-known nerve agent simulant (dimethylmethylphosphonate, DMMP) via hydrogen bond is reported. UV/Vis measurements indicate the formation of 1:1 complexes. 1H-, 31P-NMR titrations and T-ROESY experiments confirm that oximes bind the organophosphate via hydrogen bond.
Andrea Pappalardo1 Maria E Amato1 Francesco P Ballistreri1 Valentina La Paglia Fragola1 Gaetano A Tomaselli1 Rosa Maria Toscano1 Giuseppe Trusso Sfrazzetto1
Volume 135, 2023
All articles
Continuous Article Publishing mode
Click here for Editorial Note on CAP Mode
© 2022-2023 Indian Academy of Sciences, Bengaluru.