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      https://www.ias.ac.in/article/fulltext/jcsc/125/03/0517-0524

    • Keywords

       

      Thioisatin; chalcones; benzodiazocines; spiropyrans; DFT calculations; transition state.

    • Abstract

       

      Syntheses of 3-(phenyl)-benzo[b]thiophene [2, 3-d][1,2] benzodiazocine derivatives have been accomplished by the reaction of 3-phenacylidine-2-benzo[b]thiophene-2-ones with o-phenylene diamine. The photolytic reaction with trans-stilbene resulted in the exclusive formation of spiro{2',5',6'-triphenyl-2H-pyran-4',3}-benzo[b]thiophene-2-one derivatives. Theoretical calculations have been performed to study the mechanism and stereoselectivity of products. Good yield and broad scope of usable substrates of industrial relevance are other prominent features of the present methodologies.

    • Author Affiliations

       

      Johnson George1 Saurabh Singh1 Rahul Joshi1 Ramchand T Pardasani2

      1. Department of Chemistry, University of Rajasthan, Jaipur 302 055, India
      2. Department of Chemistry, Central University of Rajasthan, Bandarsindri, Ajmer 305 802, India
    • Dates

       
  • Journal of Chemical Sciences | News

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