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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/124/05/1057-1062

    • Keywords

       

      Ultrasound irradiation; Rongalite® 𝛽-hydroxy sulphides; epoxides; ring-opening reaction.

    • Abstract

       

      Rongalite® promotes cleavage of diaryl disulphides generating the corresponding thiolate species in situ which then undergo facile ring-opening of epoxides in a regioselective manner under ultrasound irradiation, affording 𝛽-hydroxy sulphides in good to excellent yields. The important features of this methodology are base-free, odourless, high yield, reasonably rapid reaction rate, simple workup, high regioselectivity, costeffective and no requirement of transition metal catalysts. It is noteworthy that ring-opening reaction of 1,2-diphenyldiselane with 2-(phenoxymethyl)oxirane are also conducted smoothly to afford 𝛽-hydroxy selenide in excellent yield under the standard conditions.

    • Author Affiliations

       

      Guang-Shu Lv1 Fu-Junduan1 Jin-Chang Ding1 2 Tian-Xing Cheng1 Wen-Xia Gao1 Jiu-Xi Chen1 Hua-Yue Wu1

      1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China
      2. Wenzhou Vocational and Technical College, Wenzhou, 325035, P. R. China
    • Dates

       
  • Journal of Chemical Sciences | News

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