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    • Di(1𝐻-benzo[𝑑][1,2,3]triazol-1-yl)methane: An efficient ligand for copper and amine-free palladium-catalysed Sonogashira coupling reaction

      Jaspal Singh Akhilesh Kumar Verma

      Volume 123 Issue 6 November 2011 pp 937-942

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/123/06/0937-0942

    • Keywords

       

      Palladium; terminal alkynes; benzotriazole; amine-free; copper-free.

    • Abstract

       

      An efficient Pd-catalysed Sonogashira coupling reaction was achieved in the absence of copper and amine with inorganic base using phosphene-free, air stable di(1𝐻-benzo[𝑑][1,2,3]triazol-1-yl)methane as ligand. The cross coupling of electron-rich, electron-defficient and hindered aryl halides with terminal alkynes afforded the internal alkynes in good to excellent yields.

    • Author Affiliations

       

      Jaspal Singh1 Akhilesh Kumar Verma1

      1. Synthetic Organic Chemistry Research Laboratory, Department of Chemistry, University of Delhi, Delhi 110007, India

    • Dates

       
      Published
      November 2011

    • Supplementary Material

       

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