• Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/123/04/0491-0495

    • Keywords

       

      Unsaturated steroidal ketones; DMAP; amine catalysed dimerization; xylene; steroidal dimers.

    • Abstract

       

      Some new dimeric steroids namely cholest-5-en-3-spiro-[6'𝛼,5'-oxa]-5'$\alpha$-cholest-3'-one (2), cholest-5-en-7-spiro-[4'𝛼,5'-oxa]-5'𝛼-cholest-7'-one (4a) and 3𝛽-substitutedcholest-5-en-7-spiro-[4'𝛼,5'-oxa]-3'𝛽-substituted-5'𝛼-cholestan-7'-ones (4b, c) are synthesized starting from cholest-5-en-3-one (1), cholest-5-en-7-one (3a) and 3𝛽-substituted-cholest-5-en-7-ones (3b, c) respectively by using DMAP and xylene. All the synthesized compounds were characterized by using IR, MS and 1H, 13C NMR spectral and elemental analysis.

    • Author Affiliations

       

      Shamsuzzaman1 Mohd Gulfam Aalam1 2 Tabassum Siddiqui1

      1. Department of Chemistry, Faculty of Science, Aligarh Muslim University, Aligarh 202 002, India
      2. School of Distance Education (Chemical Science Programme), Universiti Sains Malaysia, Minden, Palau Pinang 11800, Malaysia
    • Dates

       
  • Journal of Chemical Sciences | News

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2017-2019 Indian Academy of Sciences, Bengaluru.