Synthesis, spectroscopic characterization and catalytic oxidation properties of ONO/ONS donor Schiff base ruthenium(III) complexes containing PPh3/AsPh3
Priyarega M Muthu Tamizh R Karvembu R Prabhakaran K Natarajan
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Six different ruthenium(III) complexes of Schiff bases derived from 2-hydroxy-1-naphthaldehyde and 𝑜-aminophenol/𝑜-aminothiophenol have been synthesized. The compounds with the general formula [RuX(EPh3)2(L)] (X = Cl or Br; E = P or As; L = bifunctional tridentate ONO/ONS donor Schiff base ligand) were characterized by infrared, electronic, electron paramagnetic resonance spectroscopy and elemental analyses. Spectroscopic investigation reveals coordination of Schiff base ligand through ONO/ONS donor atoms and octahedral geometry around ruthenium metal. Redox property of complexes has been examined by using cyclic voltammetry. The catalytic oxidation property of ruthenium(III) complexes were also investigated.
Priyarega1 M Muthu Tamizh2 R Karvembu2 R Prabhakaran1 K Natarajan1
Volume 135, 2023
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