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    • Keywords


      Kinetics; palladium(II); diethyldithiocarbamate; mechanism; activation parameters.

    • Abstract


      The kinetics of the interaction between diethyldithiocarbamate (Et2DTC) and the title complex has been studied spectrophotometrically in aqueous medium as a function of nucleophile concentration, temperature and pH at constant ionic strength. The reaction is a two-step process in which the first step is liganddependent, but the second step is ligand-independent and is assigned to ring closure. The rate and activation parameters, conductivity studies and IR data were used to deduce a plausible mechanism.

    • Author Affiliations


      Subhasis Mallick1 Biplab K Bera1 Subala Mondal1 Parnajyoti Karmakar1 Arup Mandal1 Alak K Ghosh1

      1. Department of Chemistry, The University of Burdwan, Burdwan 713104, India
    • Dates

  • Journal of Chemical Sciences | News

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