• Fulltext


        Click here to view fulltext PDF

      Permanent link:

    • Keywords


      Polarization dependent differential cross-section (PDDCS); vector correlation; quasiclassical trajectory method; stereodynamics; integral cross section.

    • Abstract


      Integral cross-section and stereodynamics study of the reaction O(1D)+H2($v = 0$, $j = 0$) → OH + H is undertaken using the quasiclassical trajectory (QCT) method for the collision energy is in the large length of 1.3 to 43 kcal/mol using Dobbyn and Knowles (DK) surface, and the obtained results are compared with those available from earlier available calculated results on the BR surface. The integral cross sections obtained from the quasiclassical trajectory method are in good agreement with those of Chebyshev wave packet method for collision energies above 0.2 eV.We also investigated the vector correlations and polarized dependent differential cross sections (PDDCS) at different collision energies. It is demonstrated that the alignment and state distribution significantly decrease with increase in the collision energy.

    • Author Affiliations


      Tianyun Chen1 Ningjiu Zhao1 2 Weiping Zhang1 Dongjun Wang2 Xinqiang Wang3

      1. School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
      2. Department of Chemistry, Hebei Normal University of Science and Technology, Qinhuangdao 066600, China
      3. College of Physics, Chongqing University, Chongqing 400044, China
    • Dates

  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.