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    • Keywords


      M-C bond cleavage; metallophilic; secondary bonding intramolecular interaction; organochalcogen; telluroxane; transmetallation.

    • Abstract


      Recent trends in the area of intramolecularly coordinated organomercury and organochalcogens derivatives are reviewed. Intramolecular coordination in organomercury derivatives facilitates the formation of mercurametallamacrocycle and leads to novel metal-metal interaction with closed shell ions. It also plays a key role in stabilizing telluroxanes as well as in the activation of chalcogen-carbon bonds.

    • Author Affiliations


      Sagar Sharma1 Tapash Chakraborty1 Kriti Srivastava1 Harkesh B Singh1

      1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India
    • Dates

  • Journal of Chemical Sciences | News

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      Posted on July 25, 2019

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