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    • Fulltext

       

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      https://www.ias.ac.in/article/fulltext/jcsc/123/02/0113-0122

    • Keywords

       

      M-C bond cleavage; metallophilic; secondary bonding intramolecular interaction; organochalcogen; telluroxane; transmetallation.

    • Abstract

       

      Recent trends in the area of intramolecularly coordinated organomercury and organochalcogens derivatives are reviewed. Intramolecular coordination in organomercury derivatives facilitates the formation of mercurametallamacrocycle and leads to novel metal-metal interaction with closed shell ions. It also plays a key role in stabilizing telluroxanes as well as in the activation of chalcogen-carbon bonds.

    • Author Affiliations

       

      Sagar Sharma1 Tapash Chakraborty1 Kriti Srivastava1 Harkesh B Singh1

      1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India

    • Dates

       
      Published
      March 2011

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      Posted on July 25, 2019

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