• A quasiclassical trajectory analysis of stereodynamics of the H+FCl ($v=0- 3$, $j=0- 3$) → HCl+F reaction

• # Fulltext

https://www.ias.ac.in/article/fulltext/jcsc/123/01/0021-0027

• # Keywords

Quasiclassical trajectory method; chemical stereodynamics; polarization-dependent differential cross sections.

• # Abstract

The chemical stereodynamics for the title reaction are studied by the quasiclassical trajectory method. Employing the recent works of Deskevich, Hayes, Takahashi, Skodje, and Nesbitt (DHTSN) potential energy surface of the ground $1^2$A' electronic state, the present work calculates the polarizationdependent differential cross sections and the three angular distributions which describe the vector correlations among the product angular momentum j' and the reagent and the product initial relative velocities k and k'. The effect of vibrational and rotational excitations for the reagent FCl and the influence of collision energies on the stereodynamical quantities are also investigated and discussed.

• # Author Affiliations

1. Department of Physics and Information Engineering, Jining University, Qufu 273155, China
2. College of Physics and Information Engineering, Shanxi Normal University, Linfen 041004, China

• # Journal of Chemical Sciences

Volume 134, 2022
All articles
Continuous Article Publishing mode

• # Editorial Note on Continuous Article Publication

Posted on July 25, 2019