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    • Keywords


      Synthesis; spectra; aggregation; chirality.

    • Abstract


      The optically active tetra-𝛽-[(𝑆)-2-octanyloxy]-substituted copper and nickel phthalocyanines were synthesized via a two-step route with 4-nitro-phthalonitrile and (𝑆)-2-octanol as the starting materials. Both compounds are fully characterized by MS, 1H NMR, UV-Vis, IR, CD and elemental analysis, and soluble in common organic solvents except methanol. The results showed that they were dispersed into single molecules in chloroform and dichloromethane, but prone to congregate into H-type aggregates in ethanol and diethyl ether. They assembled to H-type aggregates with left-handed helix when deposited as thin films.

    • Author Affiliations


      Fang-Di Cong1 2 Gui Gao3 Jian-Xin Li2 Guo-Qing Huang2 Zhen Wei1 Feng-Yang Yu1 Xi-Guang Du1 2 Ke-Zhi Xing1

      1. Tianjin Key Laboratory of Aqua-ecology and Aquaculture, Department of Basic Sciences, Tianjin Agricultural University, Tianjin 300384, China
      2. Faculty of Chemistry, Northeast Normal University, Changchun 130024, China
      3. Key Laboratory for Molecular Enzymology and Engineering of Ministry of Education, Jilin University, Changchun 130021, China
    • Dates

  • Journal of Chemical Sciences | News

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