• Suzuki-Miyaura, Mizoroki-Heck carbon-carbon coupling and hydrogenation reactions catalysed by PdII and RhI complexes containing cyclodiphosphazane cis-{$^t$BuNP(OC6H4OMe-𝑜)}2

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      https://www.ias.ac.in/article/fulltext/jcsc/122/02/0137-0142

    • Keywords

       

      Cyclodiphosphazane; catalysis; palladium and rhodium complexes; Suzuki-Miyaura reactions; Mizoroki-Heck reactions; hydrogenation reactions.

    • Abstract

       

      The catalytic activity of the palladium complex cis-[PdCl2{($^t$BuNP(OC6H4OMe-𝑜))2-$\kappa P$}2] (2) containing cis-{$^t$BuNP(OC6H4OMe-𝑜)}2 (1) in Suzuki-Miyaura and Mizoroki-Heck carbon-carbon cross coupling reactions is described. The compound 2 also displays very high activity in Mizoroki-Heck coupling reactions. The rhodium(I) complex [RhCl(COD){($^t$BuNP(OC6H4OMe-𝑜))2-$\kappa P$}] (3) acts as an excellent catalyst for the hydrogenation of several terminal olefins.

    • Author Affiliations

       

      Sasmita Mohanty1 Maravanji S Balakrishna1

      1. Phosphorus Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400 076
    • Dates

       
  • Journal of Chemical Sciences | News

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