• Suzuki-Miyaura, Mizoroki-Heck carbon-carbon coupling and hydrogenation reactions catalysed by PdII and RhI complexes containing cyclodiphosphazane cis-{$^t$BuNP(OC6H4OMe-𝑜)}2

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    • Keywords


      Cyclodiphosphazane; catalysis; palladium and rhodium complexes; Suzuki-Miyaura reactions; Mizoroki-Heck reactions; hydrogenation reactions.

    • Abstract


      The catalytic activity of the palladium complex cis-[PdCl2{($^t$BuNP(OC6H4OMe-𝑜))2-$\kappa P$}2] (2) containing cis-{$^t$BuNP(OC6H4OMe-𝑜)}2 (1) in Suzuki-Miyaura and Mizoroki-Heck carbon-carbon cross coupling reactions is described. The compound 2 also displays very high activity in Mizoroki-Heck coupling reactions. The rhodium(I) complex [RhCl(COD){($^t$BuNP(OC6H4OMe-𝑜))2-$\kappa P$}] (3) acts as an excellent catalyst for the hydrogenation of several terminal olefins.

    • Author Affiliations


      Sasmita Mohanty1 Maravanji S Balakrishna1

      1. Phosphorus Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400 076
    • Dates

  • Journal of Chemical Sciences | News

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      Posted on July 25, 2019

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